Autunite

IMA-GP
Uranium 40.2a.1.1
(Dana Classification Number)
(No Images) 7/E.01-90
(Strunz ID)


Unless sealed in glass, all specimens should be considered to have become Meta-Autunite within a few months of being exposed to ambient air. (See Notes for more information).

Property Data Remarks
Named for: Autun, France, its type locality
Alternate
    Name(s):
  • Lime Uranite
  • Calcium Autunite
 
Mineral Class:
Phosphates, Arsenates and Vanadates
  Uranylphosphates and uranylvanadates with
[UO2]2+ - [PO4 | AsO4]3- and
[UO2]2+ - [V2O8]6-
    Autunite group
 
Chemical
    Formula:
Ca(UO2)2(PO4)2 . 10-12H2O  
Chemical
    Composition:
Calcium: (Ca) 4.06%
Hydrogen: (H) 2.45%
Oxygen: (O) 38.93%
Phosphorus: (P) 6.28%
Uranium: (U) 48.27%
by weight
Molecular
    Weight:
986.26 daltons (amu)
Specific
    Radioactivity:

(All radiation is for a 1 gram, fully aged specimen)

Specific Activity Dose Rate
Becquerels Curies  milliRems 
hour
 microSieverts 
hour
8.6402 × 1004 2.34 × 10-06 1.23 123.44

Estimated Average Annual Exposure: 360 mRem (3.6 milliSieverts)

Crystalography:
System: Tetragonal - Ditetragonal Dipyramidal
Axial Ratios: a: 1
c: 2.95848
Cell Dimensions: a: 7.009 Å
c: 20.736 Å
Z: 2
V: 1,018.68 Å3
DenCalc: 3.22
H-M Symbol: 4/m 2/m 2/m
Space Group: I4/mmm
X-Ray Diffraction:
  By Intensity ( I/Io )
(1): 10.3 Å
(0.8): 4.96 Å
(0.7): 3.59 Å
Autunite
Crystal
Habit:
  • Tabular square crystals dominated by two pinacoid faces. Crystals are often in parallel growths that can have a "fanned-out" look or in rosetta clusters
  • Micaceous
  • Foliated
  • Crusts and earthy masses
  •  
    Cleavage:
    [001] Perfect
    [010] Poor
    [001] Poor
     
    Fracture: Uneven  
    Moh's
        Hardness:
    2 - 2.5  
    Density: 3.1 - 3.2 grams/cm3
    Color:

    Pale yellow to Yellow to Bright "lemon" yellow to Greenish yellow to Pale green to Green.

    Often showing a mixture of yellow and green shades in one specimen.

     
    Streak: Pale yellow to Yellow  
    Luster: Vitreous to Pearly, on the main pinacoid.
    Subadamantine elsewhere.
     
    Diaphaniety: Transparent to Translucent  
    Pleochroism:
    (x):  
    (y:)  
    (z:)  
     
    Ultra Violet
        Fluorescence:
    Long Wave: Yellow to Yellow-green
    Short Wave: Yellow to Yellow-green
     
    Magnetism: Non-magnetic  
    Occurance:
  •  
    Associated
        Minerals:

    Secondary mineral to Uraninite. Also Torbernite, Metatorbernite, Uranocircite, Uranophane and other uranium minerals.

    Minerals   -   Uranium & Thorium
    mineral links

    These are minerals known to be found with Autunite
    Localities:

    Relatively common Uranium mineral

    Autunite Localities

    Notes:

    Strongly radioactive a- and b-particles, g-rays.

    Crystals are probably metamic.

    Thin crystals or cleavage sheets are bendable.

    Autunite can lose water and convert to a different mineral called Meta-Autunite-I of the Meta-Autunite/Metatorbernite group of minerals. With heating, it can produce a Meta-Autunite-II mineral. Neither mineral is found in nature in any appreciable abundance. The conversion is irreversible (see below) and ongoing, and all specimens exposed to ambient air for several months are at least partially converted. Eventually, after many years, the Meta-Autunite will turn to powder.

    When Autunite dehydrates, the crystals fracture into extremely fine fragments of the mineral Meta-Autunite. These fragments retain the general form of Autunite, and are therefore a pseudomorph of Autunite. While the dehydration can can be reversed, rehydrating back to Autunite, the fragments do not fuse back into a single crystal. When rehydrated, the Autunite becomes, in effect, a pseudomorph of itself. The x-ray diffraction pattern of the rehydrated Autunite will be that of Autunite, but will be somewhat blurred due to slight misalignment of the crystal fragments.

    Unless done very slowly and carefully, rehydration of Meta-Autunite will cause the re-expanding crystals to push apart, and the pseudomorph crystal to break up. It is believed that over years of dehydration/rehydration cycling is the cause of specimens turning to powder.