Thorogummite

IMA-GP
Uranium (trace)
Thorium
51.5.2.5
(Dana Classification Number)
(Images) 8/A.09-50
(Strunz ID)

Property Data Remarks
Named for: Its Thorium content and gum-like consistancy
Alternate
    Name(s):
  • alpha-Hyblite
  • beta-Hyblite
  • Chlorothorite
  • Hyblite
  • Hydrothorite
  • Hydroxyl-thorite
  • Mackintoshite
  • Maitlandite
  • Nicolayite
  • Pilbarite (a mixture of Kasolite and Thorogummite)
  • These minor varients of Thorogummite were once considered to be seperate minerals
    Mineral Class:
    Silicates
      Nesosilicates with [SiO4]-4 groups,
    cations of octahedral and cubic orientation [8+6]
        Zircon - Thorogummite series
     
    Chemical
        Formula:

    (Th, U)2(SiO4)(2 - X)(OH)4X

    Thorogummite has varying amounts of SiO4 tetrahedrons that are replaced by four hydroxides. This can be represented with several different formulas. The formula that is used here:

    (Th, U)2(SiO4)(2 - X)(OH)4X

    The X represents the conversion of one silicate tetrahedron with a negative four charge (-4) to four hydroxides with a negative one charge (-1) each. So that if half the silicate tetrahedrons are replaced by the four hydroxides, where X = 1, the formula would look like this:

    (Th, U)2SiO4(OH)4

    Often though thorogummite's formula is written like this:

    (Th, U)[SiO4, (OH)4]

    This formula also reflects the substitution of hydroxides for silicate tetrahedrons.

     
    Chemical
        Formula:
    Th(SiO4)1-x(OH)4x Thorium Hydroxy Silicate
    Chemical
        Composition:
    Hydrogen: (H) 0.13%
    Oxygen: (O) 19.89%
    Silicon: (Si) 7.86%
    Thorium: (Th) 72.13%
    by weight
    Molecular
        Weight:
    321.72 daltons (amu)
    Specific
        Radioactivity:

    (All radiation is for a 1 gram, fully aged specimen)

    Specific Activity Dose Rate
    Becquerels Curies milliRems/hour microSieverts/hour
    3.2312 × 1004 8.73 × 10-07 0.42 42.45

    Estimated Average Annual Exposure: 360 mRem (3.6 milliSieverts)

    Crystalography:
    System: Tetragonal- Ditetragonal Dipyramidal
    Axial Ratios: a:c = 1:0.88568
    Cell Dimensions: a = 7.068, c = 6.26, Z = 3; V = 312.73 Den(Calc)= 5.12
    H-M Symbol: 4/m 2/m 2/m
    Space Group: I41/amd
    X Ray Diffraction: By Intensity(I/Io): 3.537(1) 4.695(0.9) 2.653(0.6)
     
    Habit:
    • Earthy masses
    • Pseudomorphs of thorite, (short prismatic crystals with a square cross-section and simple pyramidal terminations. On-hand specimen observed with some having a slightly octahedral cross-sections)
     
    Cleavage: Absent  
    Fracture: Earthy  
    Moh's
        Hardness:
    5 (1 - en mass)  
    Density: 4.1 - 4.5 (5.4) grams/cm3
    Color: Pale yellow, Yellowish brown, White, Buff, Brown, Greenish gray, or Black  
    Streak: Pale yellow to White  
    Luster: Earthy to Vitreous  
    Diaphaneity: Opaque  
    Pleochroism: None  
    Ultra Violet
        Fluorescence:
    Non-fluorescent  
    Magnetism: Non-magnetic  
    Occurance:
  • Secondary modification of Thorite.
  •  
    Associated
        Minerals:

    Aegirine, Albite, 'Allanite', Almandine, Anatase, 'Apatite', Arsenopyrite, Augite, Barite, Beryl, Biotite, Calcite, Cancrinite, Celestine, Chalcopyrite, 'Chlorite Group', Clinochlore, Diopside, Dolomite, Fluorapatite, Fluorite, 'Gadolinite', Galena, Goethite, Graphite, Gypsum, Hematite, 'Hornblende', Ilmenite, Magnetite, Malachite, Marcasite, Microcline, Molybdenite, Monazite, Muscovite, Nepheline, 'Oligoclase', Orthoclase, Pyrite, Pyrochlore, Pyrrhotite, Quartz, Quartz var: Smoky Quartz, Rutile, Siderite, Spessartine, Sphalerite, Talc, Thorite, Titanite, Tremolite, Uraninite, Uranophane, Wulfenite, Xenotime-(Y), Zircon

    Mineral   -   > 60% of sites
    Mineral   -   > 40% of sites
    Mineral   -   > 20% of sites
    Minerals   -   Uranium & Thorium
    mineral links

    These are minerals known to be found with Thorogummite
    Locations:

    Somewhat rare

    Thorogummite Locations

    The type locale is now inundated by Buchanan artifical Lake, along the Colorado River, Texas, U.S.A.

    Notes:

    Strongly radioactive a- and b-particles, g-rays. Always metamict.

    A product of the alteration of thorite, (Th, U)SiO4

    Thorogummite Images

    Specimen
    (001a) (001b) (001c) (001d)
    (001e) (001f) (001g) (001h)
    (001i) (001j) (001k) (001l)
    (001m) (001n) (001o) (001p)
    (001q) (001r) (001s)
    Fort Dauphin (Tôlanaro) area, Toliara (Tuléar) Province, Madagascar


    Specimen Notes

    Host Matrix - The matrix that the Thorogummite occurs in is primarily Calcite and Quartz. There appears to be very few, if any, vugs in the rock. The Thorogummite appears to have grown cuncurrently with the host rock.

    Crystals - There are no true crystals of Thorogummite visable anywhere on the specimen. The Thorogummite occurs as either massive deposits or crystal pseudomorphs after Thorite, which is to be expected as it is a thorite chemically combined with water, and not simply hydrated. The massive deposits occur in two forms: sub-opague light 'apricot' yellow ; or crystaline, translucent to sub-transparent light to dark 'apricot' yellow (bottom center of image 001b and image 001e). The lighter colored crystaline massive forms often appear to be cloudy, as in image 001h. The two forms may occur intermixed together, as seen in image 001m.

    The crystal pseudomorphs after Thorite are in the prismatic form of Thorite. These pseudomorphs can be seen in images 001a and 001f, and 001n thru 001s. They are somewhat erroded and rounded, with the pointed tips all definitely rounded. The lateral edges of the crystal body appear to be truncated in addition to being rounded, as can be seen in images 001o, 001p and 001s. It is possible that this is due to the erosion of the thorogummite during its formation.

    Diaphaneity - The Thorogummite varies from transparent to translucent, as seen in image (001j). The pseudomorph crystals are mostly translucent, with a few areas opaque, seen in image (001o).

    Luster - Luster varies from vitreous, image (001j), to sub-vitreous, image (001p). The more transparent Thorogummite is also the more vitreous. The opaque Thorogummite is earthy in luster.

     

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